Electron microprobe analyses of sphalerite and hemimorphite from mine wastes from the Tar Creek Superfund Site, Tri-State Mining District, Oklahoma, U.S.A.
Electron microprobe analyses of sphalerite (ZnS) and hemimorphite (Zn4Si2O7(OH)2·H2O) from sampled historical waste piles were conducted with a specific focus on germanium (Ge). In mine wastes at the Tar Creek Superfund Site, Oklahoma, USA, Ge is associated with ZnS (sphalerite) as expected, but weathering in the …